Tic layers have been successfully deposited locally on D2 tool steel specimens and miniature industrial tools with the aim to improve their
mechanical and chemical surface properties. The deposition process was based on a pyrolytically-induced chemical reaction of Tick, and
CC& compounds combined with an atomic hydrogen source. Local heating of the substrate was achieved by means of a 100 W COz laser
controlled by a microcomputer-based feedback loop system, involving on-line substrate temperature monitoring. Scanning electron microscopy,
energy-dispersive X-ray analysis, X-ray diffraction, and transmission electron microscopy analysis showed that close-stoichiometric
Tic (fee structure, lattice constant a =4.2 A) was deposited in the films with a nanocrystalline structure. The microhardness of the coatings
was in the range 2500-3200 HK.