Vapor-induced swelling of supported methacrylic and siloxane polymer films

dc.contributor.author	Μανώλη, Κυριακή	el
dc.contributor.author	Γουστουρίδης, Δημήτριος	el
dc.contributor.author	Ράπτης, Ιωάννης Α.	el
dc.contributor.author	Βαλαμόντες, Ευάγγελος Σ.	el
dc.contributor.author	Σανοπούλου, Μερόπη	el
dc.date.accessioned	2015-05-18T16:09:26Z
dc.date.available	2015-05-18T16:09:26Z
dc.date.issued	2015-05-18
dc.identifier.uri	http://hdl.handle.net/11400/10670
dc.rights	Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/us/	*
dc.source	http://eu.wiley.com/	en
dc.subject	Polymethacrylates
dc.subject	Polysiloxanes
dc.subject	Swelling
dc.subject	Thin polymer films
dc.subject	Vapor sorption
dc.subject	White light reflectance spectroscopy
dc.subject	Φασματοσκοπία αντανάκλασης λευκού φωτός
dc.subject	Οίδημα
dc.subject	Πολυμεθακρυλικοί
dc.subject	Πολυσιλοξάνια
dc.subject	Λεπτά υμένια πολυμερούς
dc.subject	Προσρόφηση ατμών
dc.title	Vapor-induced swelling of supported methacrylic and siloxane polymer films	en
heal.type	journalArticle
heal.secondaryTitle	determination of interaction parameters	en
heal.classification	Technology
heal.classification	Chemical technology
heal.classification	Τεχνολογία
heal.classification	Χημική τεχνολογία
heal.classificationURI	http://id.loc.gov/authorities/subjects/sh85133147
heal.classificationURI	http://skos.um.es/unescothes/C00565
heal.classificationURI	N/A-Τεχνολογία
heal.classificationURI	N/A-Χημική τεχνολογία
heal.identifier.secondary	DOI: 10.1002/app.31100
heal.language	en
heal.access	campus
heal.publicationDate	2010-04-05
heal.bibliographicCitation	MANOLI, K., GOUSTOURIDIS, D., RAPTIS, I.A., VALAMONTES, E.S. & SANOPOULOU, M. (2010). Vapor-induced swelling of supported methacrylic and siloxane polymer films: determination of interaction parameters. Journal of Applied Polymer Science. [online] 116 (1). p. 184-190. Available from: http://eu.wiley.com/	en
heal.abstract	White light reflectance spectroscopy is applied to monitor vapor-induced thickness changes of polymer films, supported on suitable silicon substrates. Assuming unidirectional swelling due to the constraining support, the equilibrium volume swelling of four methacrylic polymers and two siloxane-based copolymers upon exposure to various activities of water, methanol, ethanol, and ethyl acetate vapor, at 30°C is evaluated. The deduced sorption isotherms were fitted to the Flory-Huggins equation and interaction parameters, as well as solubility coefficients at infinite solute dilution, were deduced for each binary system. The relative sorption capacity of the different classes of polymers toward the four vapors are in line with the expected solubility interactions between solvent and solute.	en
heal.publisher	Wiley	en
heal.journalName	Journal of Applied Polymer Science	en
heal.journalType	peer-reviewed
heal.fullTextAvailability	true