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dc.contributor.author Μυλωνάς, Ιωακείμ el
dc.contributor.author Τριάντης, Χαράλαμπος el
dc.contributor.author Παναγιωτοπούλου, Αγγελική el
dc.contributor.author Πάτσης, Γεώργιος Π. el
dc.contributor.author Ραφτοπούλου, Αικατερίνη Π. el
dc.date.accessioned 2015-06-07T20:19:39Z
dc.date.available 2015-06-07T20:19:39Z
dc.date.issued 2015-06-07
dc.identifier.uri http://hdl.handle.net/11400/15546
dc.rights Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/us/ *
dc.source http://www.elsevier.com/ en
dc.subject Bifunctional
dc.subject Rhenium
dc.subject Technetium
dc.subject Tricarbonyl complexes
dc.subject τρικαρβονυλικά συμπλέγματα
dc.title A new bifunctional tridentate NSN ligand leading to cationic tricarbonyl fac-[M(NSN)(CO)3]+ (M = Re, 99mTc) complexes en
heal.type journalArticle
heal.classification Technology
heal.classification Electrical engineering
heal.classification Τεχνολογία
heal.classification Ηλεκτρολογία Μηχανολογία
heal.classificationURI http://id.loc.gov/authorities/subjects/sh85133147
heal.classificationURI http://zbw.eu/stw/descriptor/18426-4
heal.classificationURI **N/A**-Τεχνολογία
heal.classificationURI **N/A**-Ηλεκτρολογία Μηχανολογία
heal.keywordURI http://id.loc.gov/authorities/subjects/sh85133086
heal.contributorName Τερζής, Αριστείδης el
heal.contributorName Ψυχάρης, Βασίλειος el
heal.contributorName Κομιώτης, Δημήτριος el
heal.contributorName Πελεκάνου, Μαρία el
heal.contributorName Πιρμέττης, Ιωάννης Χ. el
heal.contributorName Παπαδόπουλος, Μηνάς Σ. el
heal.identifier.secondary DOI: 10.1016/j.ica.2013.02.001
heal.language en
heal.access campus
heal.publicationDate 2013-05-01
heal.bibliographicCitation MILONAS, I., TRIANTIS, C., PANAGIOTOPOULOU, A., PATSIS, G.P., RAFTOPOULOU, A.P., et al. (2013). A new bifunctional tridentate NSN ligand leading to cationic tricarbonyl fac-[M(NSN)(CO)3]+ (M = Re, 99mTc) complexes. Inorganica Chimica Acta. [online] 400. p. 2-6. Available from: http://www.elsevier.com/[Accessed 09/02/2013] en
heal.abstract The synthesis and characterization of the new NSN tridentate bifunctional chelating agent 3-[2-(2′-pyridin-2-yl-ethylsulfanyl)ethylamino] propionic acid (as its hydrochloric salt, 1) and of its corresponding rhenium complex fac-[Re(NSN)(CO)3]+, 2, is described. Both compounds were characterized by elemental analysis, IR and NMR spectroscopies and X-ray crystallography. In complex 2 the coordination geometry around rhenium is distorted octahedral with the NSN atoms participating in the coordination sphere while the carboxylate group remains free. At tracer level, the analogous complex fac-[99mTc(NSN)(CO)3]+, 3, was obtained in high yield by reacting ligand 1 with the fac-[99mTc(H 2O)3(CO)3]+ precursor at pH 6.5. The structure of 3 was established by HPLC comparison to the prototype rhenium complex 2. Complex 3 is stable in solution as well as in the presence of strongly coordinating agents like histidine or cysteine. Our data indicate that ligand 1 can be used as a bifunctional NSN chelating agent in the design of potential 99mTc-radiopharmaceuticals. en
heal.publisher Elsevier en
heal.journalName Inorganica Chimica Acta en
heal.journalType peer-reviewed
heal.fullTextAvailability true


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Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες Except where otherwise noted, this item's license is described as Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες