Synthesis and structural characterization of novel neutral fac-M(CO)3(NSO) complexes (M = Re, 99mTc) with N-acetylcysteine derivatives as tridentate NSO ligands

dc.contributor.author	Καραγιώργου, Ουρανία	el
dc.contributor.author	Παπαγιαννοπούλου, Διονυσία	el
dc.contributor.author	Κυπριανίδου, Πατρίτσια	el
dc.contributor.author	Πάτσης, Γεώργιος Π.	el
dc.contributor.author	Παναγιωτοπούλου, Αγγελική	el
dc.date.accessioned	2015-06-07T21:00:18Z
dc.date.available	2015-06-07T21:00:18Z
dc.date.issued	2015-06-08
dc.identifier.uri	http://hdl.handle.net/11400/15558
dc.rights	Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/us/	*
dc.source	http://www.elsevier.com/	en
dc.subject	Carbonyls
dc.subject	Cysteine
dc.subject	Rhenium
dc.subject	Technetium-99m
dc.subject	καρβονύλια
dc.subject	κυστεΐνη
dc.subject	Ρήνειο
dc.title	Synthesis and structural characterization of novel neutral fac-M(CO)3(NSO) complexes (M = Re, 99mTc) with N-acetylcysteine derivatives as tridentate NSO ligands	en
heal.type	journalArticle
heal.classification	Technology
heal.classification	Chemical technology
heal.classification	Τεχνολογία
heal.classification	Χημική τεχνολογία
heal.classificationURI	http://id.loc.gov/authorities/subjects/sh85133147
heal.classificationURI	http://skos.um.es/unescothes/C00565
heal.classificationURI	N/A-Τεχνολογία
heal.classificationURI	N/A-Χημική τεχνολογία
heal.contributorName	Τσουκαλάς, Χαράλαμπος	el
heal.contributorName	Ραφτοπούλου, Αικατερίνη Π.	el
heal.contributorName	Πελεκάνου, Μαρία	el
heal.contributorName	Πιρμέττης, Ιωάννης Χ.	el
heal.contributorName	Παπαδόπουλος, Μηνάς Σ.	el
heal.identifier.secondary	DOI: 10.1016/j.poly.2009.05.010
heal.language	en
heal.access	campus
heal.publicationDate	2009-10-13
heal.bibliographicCitation	KARAGIORGOU, O., PAPAGIANNOPOULOU, D., KYPRIANIDOU, P., PATSIS, G.P., PANAGIOTOPOULOU, A., et al. (2009). Synthesis and structural characterization of novel neutral fac-M(CO)3(NSO) complexes (M = Re, 99mTc) with N-acetylcysteine derivatives as tridentate NSO ligands. Polyhedron. [online] 28 (15). p. 3317-3321. Available from: http://www.elsevier.com/[Accessed 13/05/2009]	en
heal.abstract	The reaction of [NEt4]2[Re(CO)3Br3] with equimolar amount of a tridentate NSO ligand in methanol leads to the formation of neutral tricarbonyl rhenium(I) complexes of the general formula Re(CO)3(NSO), where the NSO ligand is o-C5H4N-CH2CH2-S-CH2CH(NHCOCH3)COOH (L1H), complex 1 or o-C5H4N-CH2CH2-S-C(CH3)2CH(NHCOCH3)COOH (L2H), complex 2. Both complexes have been characterized by elemental analysis and spectroscopic methods, while complex 2 has also been characterized by X-rays analysis. At technetium-99m level, the corresponding fac-[99mTc(CO)3(NSO)] complexes 3 and 4, were obtained in high yield by reacting ligands L1H or L2H with the fac-[99mTc(CO)3(H2O)3]+ precursor in water. Their structure was established by chromatographic comparison to the prototype rhenium complex using high-performance liquid chromatographic techniques.	en
heal.publisher	Elsevier	en
heal.journalName	Polyhedron	en
heal.journalType	peer-reviewed
heal.fullTextAvailability	true