Spectroscopic and magnetic studies on electrogenerated mixed-valence ruthenium complexes

dc.contributor.author	Heath, Graham A.	en
dc.contributor.author	Lindsay, Alan J.	en
dc.contributor.author	Stephenson, T. Anthony	en
dc.contributor.author	Βάττης, Δημήτριος Κ.	el
dc.date.accessioned	2015-05-27T08:43:00Z
dc.date.available	2015-05-27T08:43:00Z
dc.date.issued	2015-05-27
dc.identifier.uri	http://hdl.handle.net/11400/11224
dc.rights	Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/us/	*
dc.source	http://www.sciencedirect.com/science/article/pii/S0022328X00855746#	el
dc.subject	spectroscopy
dc.subject	Magnetics
dc.subject	Valence (Theoretical chemistry)
dc.subject	Ruthenium
dc.subject	Φασματοσκοπικό
dc.subject	Μαγνητικά
dc.subject	Σθένος
dc.subject	Ρουθήνιο
dc.title	Spectroscopic and magnetic studies on electrogenerated mixed-valence ruthenium complexes	en
heal.type	journalArticle
heal.classification	Chemical technology
heal.classification	Organometallic compounds
heal.classification	Χημική τεχνολογία
heal.classification	Οργανομεταλλικές ενώσεις
heal.classificationURI	http://skos.um.es/unescothes/C00565
heal.classificationURI	http://id.loc.gov/authorities/subjects/sh85095561
heal.classificationURI	N/A-Χημική τεχνολογία
heal.classificationURI	N/A-Οργανομεταλλικές ενώσεις
heal.keywordURI	http://lod.nal.usda.gov/8493
heal.keywordURI	http://id.loc.gov/authorities/subjects/sh85079758
heal.keywordURI	http://id.loc.gov/authorities/subjects/sh85141821
heal.keywordURI	http://id.loc.gov/authorities/subjects/sh85116086
heal.identifier.secondary	ISSN: 0022328X
heal.identifier.secondary	DOI: 10.1016/S0022-328X(00)85574-6
heal.language	en
heal.access	campus
heal.recordProvider	Τεχνολογικό Εκπαιδευτικό Ίδρυμα Αθήνας. Σχολή Τεχνολογίας Τροφίμων & Διατροφής. Τμήμα Τεχνολογίας Τροφίμων	el
heal.publicationDate	1982-07-27
heal.bibliographicCitation	Heath, G. A., Lindsay, A., J. Stephenson, T. A. and Vattis, D. K. (1982). Spectroscopic and magnetic studies on electrogenerated mixed-valence ruthenium complexes. "Journal of Organometallic Chemistry", 233(3), 27 July 1982. pp 353-358. Available from: http://www.sciencedirect.com/science/article/pii/S0022328X00855746#. [Accessed 08/06/2001]	en
heal.abstract	Electrochemical synthesis has enabled several sequences of triple chloride bridged diruthenium complexes of general type [L3-xClxRuCl3RuClyL3-y]z z+ 1 z+2 (L = soft neutral ligand) to be generated. The intervalence charge transfer bands in the optical spectra of the mixed-valence RuII,III 2 compounds and variable temperature magnetic measurements for the corresponding RuIII.III 2 complexes reveal that the degree of metal-metal interaction in these confacial bioctahedral systems decreases as the molecular asymmetry (y-x) increases.	en
heal.journalName	Journal of Organometallic Chemistry	en
heal.journalType	peer-reviewed
heal.fullTextAvailability	true