Conversions in catalytic deamination calculated by stopped-flow gas chromatography

dc.contributor.author	Βάττης, Δημήτριος Κ.	el
dc.contributor.author	Κατσάνος, Νικόλαος Α.	el
dc.contributor.author	Καραϊσκάκης, Γεώργιος	el
dc.contributor.author	Λυκουργιώτης, Αλέξιος Σ.	el
dc.contributor.author	Κοτινόπουλος, Μιχαήλ	el
dc.date.accessioned	2015-05-27T10:51:15Z
dc.date.available	2015-05-27T10:51:15Z
dc.date.issued	2015-05-27
dc.identifier.uri	http://hdl.handle.net/11400/11229
dc.rights	Αναφορά Δημιουργού-Μη Εμπορική Χρήση-Όχι Παράγωγα Έργα 3.0 Ηνωμένες Πολιτείες	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/us/	*
dc.source	http://www.sciencedirect.com/science/article/pii/S0021967300985212#	el
dc.subject	Deamination
dc.subject	Catalytic deamination
dc.subject	Καταλυτική αποαμινίωση
dc.subject	Αποαμινίωση
dc.subject	Flow gas chromatography
dc.subject	Ροή του αερίου χρωματογραφίας
dc.title	Conversions in catalytic deamination calculated by stopped-flow gas chromatography	en
heal.type	journalArticle
heal.classification	Chemical technology
heal.classification	Gas chromatography
heal.classification	Χημική τεχνολογία
heal.classification	Αέριος χρωματογραφία
heal.classificationURI	http://skos.um.es/unescothes/C00565
heal.classificationURI	http://id.loc.gov/authorities/subjects/sh85053278
heal.classificationURI	N/A-Χημική τεχνολογία
heal.classificationURI	N/A-Αέριος χρωματογραφία
heal.keywordURI	http://id.loc.gov/authorities/subjects/sh85036076
heal.identifier.secondary	ISSN: 00219673
heal.identifier.secondary	DOI: 10.1016/S0021-9673(00)98521-2
heal.language	en
heal.access	campus
heal.recordProvider	Τεχνολογικό Εκπαιδευτικό Ίδρυμα Αθήνας. Σχολή Τεχνολογίας Τροφίμων & Διατροφής. Τμήμα Τεχνολογίας Τροφίμων	el
heal.publicationDate	1981-09-25
heal.bibliographicCitation	Vattis, D. K., Katsanos, N. A., Karaiskakis, G., Lycourghiotis, A. S. and Kotinopoulos, M. (1981). Conversions in catalytic deamination calculated by stopped-flow gas chromatography. "Journal of Chromatography A", 214(2), 25 September 1981. pp 171-176. Available from: http://www.sciencedirect.com/science/article/pii/S0021967300985212#. [Accessed 05/11/2001]	en
heal.abstract	By calculating absolute values for the intercepts of the rate equation that describes the deamination of aminocyclohexane on aluminium oxide, the components of a weighted mean rate constant can be found. From these the conversion of the reactant amine to product(s) can be computed, and this is in good agreement with the conversion determined directly by separate experiments. This is an indication of the internal consistency of the theoretical rate equation, derived on the basis of a particular reaction model with many kinds of active sites. The conversions are much less than 100%, showing that a considerable fraction of the reactant is adsorbed on sites which transform it to irreversibly adsorbed products. The conversion to gaseous cyclohexene increases with increasing flow-rate of the carrier gas. Finally, it was found that the effective duration of the stops is very different from the real duration.	en
heal.journalName	Journal of Chromatography A	en
heal.journalType	peer-reviewed
heal.fullTextAvailability	true